y*****s 发帖数: 1047 | 1 surface fluorination may help |
|
|
|
t******t 发帖数: 3045 | 4 这想法就是一拍脑子, 花两个星期证明行不通你也没啥损失
不用整玻璃了,直接把PDMS浇不粘锅,再灌水,干了看看上面和底下有没有区别吧
一个材料搞又亲水又疏水可以参见江雷 |
|
m****a 发帖数: 96 | 5 可以试试既有亲水又有憎水group的polymer。不过即使开始根据你的template
organize了,一分开估计很容易reorganize。PDMS肯定不行。
template |
|
|
r**x 发帖数: 408 | 7 水的600nm的峰会随着激发波长改变位置,样品的600nm的峰是它本身所具有的肩峰。C=
C是从哪儿来的呢?我的基质是SILICA GEL,不是PDMS啊。求解惑 |
|
|
q****i 发帖数: 6923 | 9 Preparation and characterization of PDMS emulsion/silica gel hybrid water
dispersions
Youjigui Cailiao (2011), 25, (5), 306-310. |
|
k***g 发帖数: 4904 | 10 不是,纯硅橡胶,比如PDMS,就非常透气,难道是因为主链是硅氧键,就透气了?
反过来,做内胎,气球,套套之类的橡胶,拉伸好几倍都不透气,还是没有解释为什么
不透气啊 |
|
y****i 发帖数: 1504 | 11 了解不够仔细啊。pdms是疏水,但是透水蒸汽,不是长期才有变化。这是一大卖点,很
多衣服涂一层这个就防水加透气了。
为啥透气,前面有个同学答对了,是因为Si-O键的缘故,一是键长长,二是键角大。 |
|
b*******H 发帖数: 830 | 12 Job title: Senior Research Fellow
Start date: Upon successful completion of selection process
FTE: Full time
Job location: Shanghai, P. R. China
Community Information:
Founded in 1953, Shanghai DianJi University (SDJU) is a public
university focused on the cultivation of students with strong practical
skills. SDJU is composed of 9 academic colleges and boasts a friendly,
supportive faculty and campus environment. Currently, the university hosts
an enrollment of over 10, 000 students includin... 阅读全帖 |
|
|
发帖数: 1 | 14 诚求审稿机会,
本人在日本取得硕博学位并有一年半博后经历,目前在美国继续博后工作,已有多次审稿
经验,最近在准备申请美国的绿卡,想继续积攒文章审稿数目,特诚求审稿机会。
主要研究方向有:
Biologically inspired materials;
Polymer biomaterials;
Surface modification;
Living radical polymerization (ATRP/RAFT);
Polymer nanoparticles and hydrogels;
Polymer therapeutics/Gene (RNA/protein) delivery systems;
Cell and material interactions;
Biosensor/biofuel cell;
Nanomedicine / Cancer therapy;
Bacterial, mammal cells and stem cells;
Laser scanning confocal microscopy;
Single cell analysis;
PDMS-b... 阅读全帖 |
|
s*******y 发帖数: 946 | 15 最近收到2份简历求帮忙推荐。公司最近不招人,另外有推荐不熟悉的人结果很失败的
先例,所以希望大家不要找我推荐工作了。写一点东西,给想在Texas Houston 找工作
的Civil Engineer同行的建议。
Texas Houston的公司每年都招很多civil / structural engineer. 推荐大家去
rigzone上面注册。上面会有猎头去搜索简历。Houston structural engineer基本上供
不应求。建议大家自己去碰运气。另外最好找认识的人推荐。
简历上,如果你有ANSYS , Abcus经验,最好写明你用这两个软件做过什么。这两个是
最常用的有限元分析软件。SAP2000, RAM Structure, SAFE这些结果软件,没有什么人
用,所以简历上提了基本没用。RISA 3D也只有很少的人用。Offshore秆件分析用SACS,
估计Civil Engineer用的也很少。
如果你用Autocad很熟练,建议你考虑学习一下 PDMS, 这里管画图的叫designer, 挣
得不比工程师少。简历注明,画图经验如何如何, 请把计算分析完... 阅读全帖 |
|
s*******y 发帖数: 946 | 16 最近收到2份简历求帮忙推荐。公司最近不招人,另外有推荐不熟悉的人结果很失败的
先例,所以希望大家不要找我推荐工作了。写一点东西,给想在Texas Houston 找工作
的Civil Engineer同行的建议。
Texas Houston的公司每年都招很多civil / structural engineer. 推荐大家去
rigzone上面注册。上面会有猎头去搜索简历。Houston structural engineer基本上供
不应求。建议大家自己去碰运气。另外最好找认识的人推荐。
简历上,如果你有ANSYS , Abcus经验,最好写明你用这两个软件做过什么。这两个是
最常用的有限元分析软件。SAP2000, RAM Structure, SAFE这些结果软件,没有什么人
用,所以简历上提了基本没用。RISA 3D也只有很少的人用。Offshore秆件分析用SACS,
估计Civil Engineer用的也很少。
如果你用Autocad很熟练,建议你考虑学习一下 PDMS, 这里管画图的叫designer, 挣
得不比工程师少。简历注明,画图经验如何如何, 请把计算分析完... 阅读全帖 |
|
s*******y 发帖数: 946 | 17 如果画图的话,要用PDMS,来Houston做石油行业的designer。 |
|
b*******H 发帖数: 830 | 18 Job title: Senior Research Fellow
Start date: Upon successful completion of selection process
FTE: Full time
Job location: Shanghai, P. R. China
Community Information:
Founded in 1953, Shanghai DianJi University (SDJU) is a public
university focused on the cultivation of students with strong practical
skills. SDJU is composed of 9 academic colleges and boasts a friendly,
supportive faculty and campus environment. Currently, the university hosts
an enrollment of over 10, 000 students includin... 阅读全帖 |
|
p********y 发帖数: 188 | 19 来自主题: Engineering版 - 面试准备 不知道你面试了没有。
首先,既然是现场面试,说明希望很大,所以一定要保持自信。
其次,每个人的面试时间大概在半小时左右,所以,如果你实在没底的话,着重你的设
计经验和使用绘图软件的经验,任何有关以往的项目,或者设计的作品都可以作为你的
谈话内容;
我假设你应聘的是:CAD designer,那么你有可能是对设计工程师负责,属于CAD
group的一员,这个design engineer在今后的工作中是你最大的接口,或就是你的直接
上司,所以尽可能展现你的设计经验。
对于工程管理监督,我假设就是project management supervisor?工程管理经理,
project manager?这两位主要是看看你的综合背景,交流能力,不会太过注重于你的
技术背景,所以你可以泛谈自己的经历,不妨什么都cover一些。
对于工艺工程师,也就是process engineer,和你的联系也会很多,是属于你support
他/她的工作的概念,也就是基本平级的,所以只要展现你积极,配合的一面就可以了。
综合而言,立足于你的设计技术背景,泛谈你的综合经历,对于软件的熟练程度(PDMS,
sol |
|
w**g 发帖数: 50 | 20 You may have a few problem in your experiemnts:
1), 5L/min flow may be too high for your SPME fiber;
2), Let the mixture stablize for some time before sampling;
3), Use "right" SPME fiber, for pinene PDMS/DVB should work;
4), Many compounds including pinene are very sensitive, even after they are
absorbed onto the SPME fiber, see if you see some degradatioon products;
5), You GC condition, especially intector condition, has huge impact on your
results;
6), Have to be consistant for your sampling... 阅读全帖 |
|
w********h 发帖数: 12367 | 21 恩,是这个样子。偶曾经用过PMA,将甲苯抽去后剩下白色弹性粘稠物,
它是rubber-like,而不是PMMA的玻璃态,而且这种rubber并不象PBD,
,PIP,PDMS一样痛痛快快就可以团在一起(Mw>Me)或者粘稠流质(Mw~
所以特别讨厌,不如给溶了算了。 |
|
|
w********h 发帖数: 12367 | 23 yes..I think PDMS can satisfy his need.
it's
using |
|
b*****h 发帖数: 29 | 24 our group want to use polymer or sol-gel mixature make some stamp so transfer
from male mask to female.
naomally guys just use PDMS but this time it must be stiff and not brittle.
does anyone have any idea?
if you really done this before or see some successful cases, please cited.
guess is also welcomed!
by the way, has anyone do sol-gel while no cracks before? |
|
c*******n 发帖数: 1648 | 25 First can you teach us why PDMS was the most used material for
microimprinting?
What's the criteria for this kind of process? Then we may come up with some
idea together by knowing this criteria for your process.
transfer |
|
w********h 发帖数: 12367 | 26 check Whitesides' papers.
PDMS is his model polymer.
brittle. |
|
c*s 发帖数: 2145 | 27 Could you please comment on the merit/limitation of PU compared with PDMS when
used as stamp?
改 |
|
p*********e 发帖数: 42 | 28 Thanks!
I have found that many people are using carbon black with some rubber (PDMS)
binder for this purpose. The conductivity certainly depends on CB content, and
good ink does need some formulation to improve the interface adhesion.
Actually, people have used this method for many years, think about your car
tires!
should
how |
|
w********h 发帖数: 12367 | 29 而且还要是amorphous,
是PDMS么? |
|
S*****n 发帖数: 6055 | 30 总之应该是polysiloxane这一类的吧
不知道有没有比PDMS更低的,呵呵 |
|
w********h 发帖数: 12367 | 31 虽然有一些人试图用Kuhn length做点文章,试图把它作为使得高分子
链行为符合高斯链行为,但仍然不够清楚,或不够General。。。究其
原因,无非是因为在大部分polymer来说,Me挺低的,下面基本上没有
多少区间可供研究,也就PS和PDMS以及他们的一些改性的东东。。。
以我的看法,现在这个问题的重点应该先解决Me和Mc的区别的根本原因,
Fetters等人曾经有几片文章(Macromolecules, JPSB)讨论过用Packing
Length去说明之间的根本原因,好久没搞这冬冬了,不知道是否为众人
接受。。。。cashine,有没有什么input?
chains
.
SOLID
for |
|
w********h 发帖数: 12367 | 32 en...
第一个问题:1+1等于几?
第二个问题:PS全称是什么?
第三个问题:写出PS的分子式。
第四个问题:PS的终极Tg是多少? Tg临界分子量是多少?
第五个问题:PS的Me是多少?Plateau modulus Gn0是多少?之间什么关系?
第六个问题:PS的Rouse区松弛时间和fluid区松弛时间的温度依赖关系相同么?PDMS呢?
他们为什么会这样?
第七个问题:请定义polymer rigidity并且说明什么链结构参数决定rigidity.
第八个问题:为什么PS和PVME是一对相容的共混物?请从热力学和分子结构决定的
dynamics两方面进行解释。
第九个问题:当人类的生命尺度变成1000岁,而不是100岁,我们的物质世界会变成什么
样子。。。 |
|
S*****n 发帖数: 6055 | 33
2
Personal Statement
-[-S-]-n
different authors have different answers which all between 100C and 105C
this morning I read a paper saying it's 374K.
Mc is around 100kg/mole
Me is slightly smaller than Mc, but they don't differ a lot.
Gn0=(nRT/Me)eta? not so sure
?
For PS Me~Mc. For PDMS Me>>Mc
cannot provide the accurate definition of rigidity...just sth to judge the
chain is easy to bend or not. Two limit situations are rod and random coil
persistence length determines rigidity
From thermodyna |
|
w********h 发帖数: 12367 | 34 en...
第一个问题:1+1等于几?
第二个问题:PS全称是什么?
第三个问题:写出PS的分子式。
第四个问题:PS的终极Tg是多少? Tg临界分子量是多少?
第五个问题:PS的Me是多少?Plateau modulus Gn0是多少?之间什么关系?
第六个问题:PS的Rouse区松弛时间和fluid区松弛时间的温度依赖关系相同么?PDMS呢?
他们为什么会这样?
第七个问题:请定义polymer rigidity并且说明什么链结构参数决定rigidity.
第八个问题:为什么PS和PVME是一对相容的共混物?请从热力学和分子结构决定的
dynamics两方面进行解释。
第九个问题:当人类的生命尺度变成1000岁,而不是100岁,我们的物质世界会变成什么
样子。。。 |
|
S*****n 发帖数: 6055 | 35
2
Personal Statement
-[-S-]-n
different authors have different answers which all between 100C and 105C
this morning I read a paper saying it's 374K.
Mc is around 100kg/mole
Me is slightly smaller than Mc, but they don't differ a lot.
Gn0=(nRT/Me)eta? not so sure
?
For PS Me~Mc. For PDMS Me>>Mc
cannot provide the accurate definition of rigidity...just sth to judge the
chain is easy to bend or not. Two limit situations are rod and random coil
persistence length determines rigidity
From thermodyna |
|
q***i 发帖数: 170 | 36 I checked sigma, and all they have are liquid. Thanks for any information! |
|
d**a 发帖数: 3715 | 37 Sylgard 184 or Silatic T2 from Dow Corning. |
|
|
|
s**********g 发帖数: 552 | 40 Dow Corning & Gelest Inc |
|
d**a 发帖数: 3715 | 41 maybe you want to google using key words like PDMS, plasma, microfluidics... |
|
|
|
|
a*i 发帖数: 1652 | 45 dow corning silicone
call them for more information |
|
w********h 发帖数: 12367 | 46 Some people did. For example, Joyce Wong's group in Biomaterials (2005); and
Teixeira et al. in Biomaterials (2009). You can modulate mechanical
properties by varying the ratio. |
|
|
|
k***g 发帖数: 4904 | 49 Polydimethylsiloxane(PDMS),就是个聚硅氧烷,没侧链只有甲基,交联后就是个硅
橡胶,经常用来cast微纳米结构。我组里有人说这东西在cure过程中可以作为
molecular imprinting的基质,通过链旋转和取向匹配模板的化学结构并固定下来成为
人工配体,用来复刻分子量级的chemical enviroment并作为sensor识别微生物类别,
可是我觉得好像这个结构很钝化啊,怎么能达到那种功能呢。因为咱对高分子是外行,
所以想来问问,这点侧链能提供明显电荷不均匀分布么?这种链在常温下能维持稳定的
取向和折叠不变么?想解释这个问题,俺该看看啥文献,或者找擅长啥计算的人聊聊呢
,高斯能很快给个大致结果么? |
|
s*********a 发帖数: 13 | 50 PDMS 是amorphous的,Tg是-90 C,医学上隆乳的材料啊。
要是在常温下维持稳定的取向和折叠不变,那岂不是。。。
修饰过的,就不知道了 |
|