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全部话题 - 话题: persulfate
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n*********e
发帖数: 665
1
来自主题: Chemistry版 - paper help
Can anyone help me with these two papers? Thanks a lot!
1)
Journal of Polymer Science
Volume 55,
Issue 162,
pages 713–719,
December 1961
Title: Polymerization of acrylamide with persulfate-metabisulfite initiator
Link:
http://onlinelibrary.wiley.com/doi/10.1002/pol.1961.1205516224/
2)
ACS Symposium Series,
Vol. 467
Chapter 5,
pp 82–104
Title: Mechanism and Kinetics of the Persulfate-Initiated Polymerization of Acrylamide
Link:
http://pubs.acs.org/doi/abs/10.1021/bk-1991-0467.ch005
M****o
发帖数: 4860
2
大家来分析一下,哪些是1作,哪些是通讯,哪些是酱油?
PUBLICATIONS since 2007
1. Q. Zhou, Z. Zhao, Y. Chen, H. Hu, J. Qiu, Low temperature plasma-mediated
synthesis of
graphene nanosheets for supercapacitor electrodes, J. Mater. Chem., 2012, in
press, doi:10.1039/C2JM15572A.
2. J. Liu, L. Yu, Z. Zhao, Y. Chen, P. Zhu, C. Wang, Y. Luo, C. Xu, A. Duan,
G. Jiang,
Potassium-modified molybdenum-containing SBA-15 catalysts for highly
efficient production of acetaldehyde and ethylene by the selective oxidation
of ethane, J. Cata... 阅读全帖
l*****8
发帖数: 16949
3
来自主题: Parenting版 - 又一个华裔起诉校方歧视的案子
吐这种酸水没意思。看看他的文章。如果你不是在大学混的,可以原谅。
PUBLICATIONS since 2007
1. Q. Zhou, Z. Zhao, Y. Chen, H. Hu, J. Qiu, Low temperature plasma-mediated
synthesis of
graphene nanosheets for supercapacitor electrodes, J. Mater. Chem., 2012, in
press, doi:10.1039/C2JM15572A.
2. J. Liu, L. Yu, Z. Zhao, Y. Chen, P. Zhu, C. Wang, Y. Luo, C. Xu, A. Duan,
G. Jiang,
Potassium-modified molybdenum-containing SBA-15 catalysts for highly
efficient production of acetaldehyde and ethylene by the selective oxidation
of ethane, J... 阅读全帖
d********O
发帖数: 1196
4
Title:Reaction of poly(vinyl alcohol) with potassium persulfate and graft
copolymerization
Volume 12, Issue 8, Date: August 1974, Pages: 1829-1839
http://www3.interscience.wiley.com/search/allsearch?mode=citation&contextLink=blah&issn=%281099-0518%2C1542-9369%2C1542-9350%2C1542-6246%2C1542-6238%29&volume=12&issue=&pages=1829
Please send to D********[email protected] , if this is more convenient for you.
Thanks again!
j**********i
发帖数: 187
5
来自主题: Chemistry版 - paper help
Article:
Study of the initiation mechanism of the vinyl polymerization with the
system persulfate/N, N, N′, N′‐tetramethylethylenediamine
Author:
Feng, Xin De
Journal:
Die Makromolekulare Chemie
ISSN:
0025-116X
Date:
1988
Volume:
189
Issue:
1
Page:
77
DOI:
10.1002/macp.1988.021890108
n******t
发帖数: 367
6
来自主题: Chemistry版 - 问个化学合成的问题
加 initiator 能把双键打开吗?例如ammonium persulfate.我化工,现在要做化学的
东西,从头学起。真晕啊。多谢你了
d**********d
发帖数: 39
7
来自主题: Environmental版 - 纽约市清洁工年薪14万
该行业不容易做假(尽管我深表怀疑),不等于Dr Hoag不做假。在UCONN的时候所领导的
ERI篡改分析数据,是导致他被UCONN除名的一个重要原因。在学术界呆不下去了就跑到
工业界,吹自己是什么什么之父,看起来很滋润,如果本性不该的话,也不知道能滋润
多久。去verutek网站一看,满眼都是Green和Nanotechnology, 公司里面有几个真正懂
这些的?从外面买来表面活性剂,加点persulfate, 包装成专利产品,捣浆糊。公司上
市很难吗?verutek06年成立,07开始赚点小钱,08就上市,09跌破谷底。
w********h
发帖数: 12367
8
【 以下文字转载自 Chemistry 讨论区,原文如下 】
发信人: YFP (cell), 信区: Chemistry
标 题: 向高分子的同学请教一个问题,acrylamide聚合的问题
发信站: The unknown SPACE (Fri Jun 6 15:47:38 2003) WWW-POST
acrylamide通过ammonium persulfate聚合, 是自由基聚合吗?
本人没有学过高分子的课,见笑了
e****m
发帖数: 8
9
Thanks for the reply.
Actually I am making Polyacrylamide gel under room temperature. My current
working formula is list below:
Acrylamide (monomer) (~ 8%, wt)
bis-acrylamide (crosslinker)
Redon: Tetramethylethylenediamine/ammonium persulfate
solvent: water/ethylene (10:1)
This formula works pretty well. However, I am trying to replace water/
ethylene glycol with pure ethylene glycol but the crosslinking cannot be
initiated even after two days. I tried to vary the reaction temperature but
it did... 阅读全帖
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