y****5
发帖数: 131 | 1 I used Pd(PPh3)4 and PdCl2(dppf). But both failed. I didn't measure out
the cat in glove box but in a cheap argon bag. Suzuki coupling with Pd(PPh3
)4 worked out for me though. |
s******g
发帖数: 2230 | 2 not super sensitive
no need for glove box, no need for argon bag, either
I used Pd(PPh3)4 and PdCl2(dppf). But both failed. I didn't measure out
the cat in glove box but in a cheap argon bag. Suzuki coupling with Pd(PPh3
)4 worked out for me though.
【在 y****5 的大作中提到】
: I used Pd(PPh3)4 and PdCl2(dppf). But both failed. I didn't measure out
: the cat in glove box but in a cheap argon bag. Suzuki coupling with Pd(PPh3
: )4 worked out for me though.
|
m****x
发帖数: 2506 | |
y****5
发帖数: 131 | 4 See attached.
【在 m****x 的大作中提到】
: no detail no truth
|
p****e
发帖数: 254 | 5 是跟文献报道的条件一样吗？你那个芳基碘会不会太富电子了，而且那个裸露的氨基也
不太好，保护一下看看 。 |
j*********5
发帖数: 6221 | 6 Pd0也许会被氧化，但是Pd2应该好很多，不会变质那么快，重新考虑保护一下底物
aniline的氨基试试，如果是催化剂问题，大不了产率低，不会fail，
PPh3
【在 y****5 的大作中提到】
: I used Pd(PPh3)4 and PdCl2(dppf). But both failed. I didn't measure out
: the cat in glove box but in a cheap argon bag. Suzuki coupling with Pd(PPh3
: )4 worked out for me though.
|
y****5
发帖数: 131 | 7 Thanks a lot for your suggestion. Sorry for the late reply. Didn't logon to
Mitbbs in the past few days.
Bt the way, is the the Stille rxn water sensitive?
【在 j*********5 的大作中提到】
: Pd0也许会被氧化，但是Pd2应该好很多，不会变质那么快，重新考虑保护一下底物
: aniline的氨基试试，如果是催化剂问题，大不了产率低，不会fail，
:
: PPh3
|
