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B****i 发帖数: 107 | 1 Fullerenes can catalyze hydrogenation of organic compounds as effectively as
metals can, according to a study by researchers in China (J. Am. Chem. Soc.
, DOI: 10.1021/ja9061097). The discovery may lead to replacing precious-
metal catalysts with carbon-based substitutes, which could reduce costs and
the environmental effects of heavy-metal pollutants.
Transition-metal catalysts lie at the heart of global-scale hydrogenation
processes, such as the ones used to refine crude oil and to synthesize | y***e 发帖数: 676 | 2 硝基还原成方向胺有3类经典方法:
1. SnCl2 + 浓HCl
2. N2H4 + 石墨 (转移加氢)
3. H2 + Pd/C (催化加氢) | B****i 发帖数: 107 | 3 我刚看到这篇文章, 说实话没觉得怎么样
主要是因为只有一个底物, 而且完全没有机理研究
没想到上了C&E news |
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