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Macromolecules版 - 统计热力学中配分函数是不是内能
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相关话题的讨论汇总
话题: energy话题: potential话题: 内能话题: partition话题: kinetic
进入Macromolecules版参与讨论
1 (共1页)
z**h
发帖数: 224
1
provided no kinetic and potential energy
o****l
发帖数: 21
2
No.

【在 z**h 的大作中提到】
: provided no kinetic and potential energy
a***n
发帖数: 578
3
it determines entropy.
内能 come from potential energy.

【在 z**h 的大作中提到】
: provided no kinetic and potential energy
z**h
发帖数: 224
4
I don't think internal energy comes from potential energy in thermodynamics.

【在 a***n 的大作中提到】
: it determines entropy.
: 内能 come from potential energy.

a***n
发帖数: 578
5
sorry. 内能 comes from potential energy + kinetic energy. (textbook)

thermodynamics.

【在 z**h 的大作中提到】
: I don't think internal energy comes from potential energy in thermodynamics.
d*********e
发帖数: 6
6

No, it is not internal energy.
Partition function is connected to free energy of the system. F=-Kb*T*lnZ.
After that you still have to know other parameters of the system to figure out
what internal energy of the system is.

【在 z**h 的大作中提到】
: provided no kinetic and potential energy
s***e
发帖数: 911
7
配分函数也决定了内能.

【在 d*********e 的大作中提到】
:
: No, it is not internal energy.
: Partition function is connected to free energy of the system. F=-Kb*T*lnZ.
: After that you still have to know other parameters of the system to figure out
: what internal energy of the system is.

c*****e
发帖数: 238
8
partition function is like doing Laplace transform to the probability
distribution function, so essentially it is related to the entropy part.

【在 z**h 的大作中提到】
: provided no kinetic and potential energy
z**h
发帖数: 224
9
Z is the partition function.Z is the sum of all energy states.

out

【在 d*********e 的大作中提到】
:
: No, it is not internal energy.
: Partition function is connected to free energy of the system. F=-Kb*T*lnZ.
: After that you still have to know other parameters of the system to figure out
: what internal energy of the system is.

1 (共1页)
进入Macromolecules版参与讨论
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A stupid question!谁熟悉kinetic monte carlo simulation?
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请问长分子链高分子和短分子链(十几个碳)混合,entropy能忽略吗?谢谢!IUPAC: ionic polymn. symposium
如何区分是A-B嵌段物还是A+B共混物?3. 浓溶液法How to do drug uptaking experiments
相关话题的讨论汇总
话题: energy话题: potential话题: 内能话题: partition话题: kinetic