p*********n
发帖数: 14 | 1 请教如图所示两单体用于水相自由基（引发剂：APS+TEMED)共聚，反应难度如何？
多谢～ | y****1
发帖数: 34 | 2 to my opinion, B would not participate as it is an electron-rich vinyl
monomer and is not very reactive under radical conditions. | d****n
发帖数: 237 | 3 我觉得能，两者先按照1：1的比例形成charge transfer complex（CTC），得到几乎为
交替结构的共聚物。如果前者的AAm过剩则可以得到交替共聚物与PAAm的混合物，如果
是后者过剩，则得到交替共聚物和残余单体B。
allyl ether就可以与马来酸酐通过自由基聚合形成alternating copolymers | t***u
发帖数: 20182 | | m*****e
发帖数: 1506 | 5 Monomer A will be homopolymerized and only small porsion of B unit will be
incorporated into the final product. Check (Q,e) values of A and B, do an
Alfrey-Price calculation, the contrast values of r1 and r2 could support
this point. |
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